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High-bandgap tandem TPV cells for conversion of >2000°C heat were developed by NREL and MIT. (Left) A TPV cell mounted on a cold-plate stage that was designed to keep the cell at 25°C despite the extremely hot environment. (Right) A blank cold plate is about to be loaded into a 2000°C furnace for a calibration measurement. Photos by Alina LaPotin, MIT.

Clean Power

Capturing Light From Heat At Record 40% Efficiency, NREL Makes Big Strides In Thermophotovoltaics

NREL’s New Cell Exceeds Previous Efficiency Record by More Than 8 Percentage Points, Unlocking More Efficient Thermal Energy Storage Applications

The National Renewable Energy Laboratory (NREL) has a long history of building solar cells that capture light from the sun at record-setting efficiencies. But the sun is not the only light source from which photovoltaics can capture energy. Hot objects emit light, too — generally at longer, lower-energy wavelengths — and thermophotovoltaics (TPVs) are photovoltaic cells that are optimized to capture that light.

A new photovoltaic cell developed by NREL far surpasses the previous, 32% world-record efficiency for TPVs. The new device, developed for a joint demonstration with the Massachusetts Institute of Technology (MIT) of an electric-energy storage concept, is described in an article in Nature.

The device developed by the NREL/MIT team consists of two light-absorbing layers, backed by a highly reflective gold mirror layer and then a heat sink. The heat sink keeps the cell from becoming too hot, which leads to a loss of efficiency. Figure adapted with permission from Alina LaPotin, MIT

The record-efficiency device, which was designed to harvest energy from an object heated to 2,400°C, reached a maximum efficiency of 41.1% (± 1%), with an average efficiency of 36.2% over a range of relevant temperatures.

“High efficiency is crucial to the engineering and economic viability of TPV systems, and this new 41% record efficiency is a giant step toward making this thermal energy grid storage concept a reality,” said Dan Friedman, an NREL author on the paper.

Improved Heat-to-Electricity Conversion Promises New Energy Storage Possibilities

Significantly, a TPV device with 40% efficiency can convert heat to electricity at greater efficiency than conventional steam turbines, such as those used in coal or nuclear power plants. TPVs offer the potential for lower costs, faster response times, compatibility with an extremely wide range of system sizes (from watts to gigawatts), and lower maintenance costs due to fewer moving parts.

The TPV cell is also optimized to operate with heat sources above 2,000°C, which are too hot for traditional steam turbines. Natural gas and hydrogen can be combusted at these temperatures, but, perhaps most importantly, low-cost, large-scale thermal energy storage systems have been envisioned to operate at these temperatures.

Thermal energy grid storage systems operate as a battery that takes in electricity and converts it to high-temperature heat for storage (think of a giant toaster). TPVs then convert that heat back to electricity when needed, providing low-cost, on-demand clean energy. The TPV device created by the team — once demonstrated in the larger joint project with MIT — could represent a crucial milestone in making clean energy storage low cost and scalable.

“So far, thermal energy grid storage has not yet gained significant attention because we’ve traditionally focused only on converting thermal energy to electric power, not the opposite,” said Zhiwen Ma, an NREL researcher leading a separate thermal energy grid storage system project unrelated to this TPV research. “Using electrical-to-thermal conversion to store energy offers great benefits in scaling energy storage and siting it where it’s needed. The development of a new world-record TPV cell improves the thermal-to-power conversion of thermal energy storage, making the technology more appealing than ever to support increasing needs for renewable integration.”

Careful Design Yields World-Record TPV Cell

The 41%-efficient TPV device is a tandem cell — a photovoltaic device built out of two light-absorbing layers stacked on top of each other and each optimized to absorb slightly different wavelengths of light. The team achieved this record efficiency through the usage of high-performance cells optimized to absorb higher-energy infrared light when compared to past TPV designs. This design builds on previous work from the NREL team.

Another crucial design feature leading to the high efficiency is a highly reflective gold mirror at the back of the cell. Much of the emitted infrared light has a longer (less energetic) wavelength than what the cell’s active layers can absorb. This back surface reflector bounces 93% of that unabsorbed light back to the emitter, where it is reabsorbed and reemitted, improving the overall efficiency of the system. Further improvements to the reflectance of the back reflector could drive future TPV efficiencies close to or above 50%.

Learn more about NREL’s work on thermophotovoltaics and high-efficiency photovoltaic devices. For further information on NREL’s TPV research, please contact Myles Steiner.

Article courtesy of the U.S. Department of Energy’s (DOE’s) National Renewable Energy Laboratory (NREL).

Featured image from related story, New Projects Move Thermophotovoltaic Technology Closer to Commercialization. Photos by Alina LaPotin, MIT.

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