Published on March 7th, 2014 | by James Ayre0
Artificial Photosynthesis — Kinetic Bottlenecks In Key Step Revealed, Improvements Coming
March 7th, 2014 by James Ayre
Significant kinetic bottlenecks in the processes of artificial photosynthesis — bottlenecks which if removed will boost the efficiency of these artificial systems — have been revealed by new research from the Lawrence Berkeley National Laboratory.
These bottlenecks were identified thanks to the researchers’ achievement of the first-ever, direct “temporally resolved observations of intermediate steps in water oxidation using cobalt oxide.” Cobalt oxide is a commonly used solid catalyst — mostly because of its relative abundance.
The development of electrocatalysts that can efficiently and economically support the water oxidation reaction is one of the ‘keys’ to the development of an economically viable artificial photosynthesis technology. The identification of these bottlenecks represents a large step towards that goal.
Researcher Heinz Frei, a chemist with Berkeley Lab’s Physical Biosciences Division, explains: “The oxidation of water to molecular oxygen is a four-electron process involving multiple steps. We’ve obtained the first direct, temporally resolved observation of two intermediate steps in water oxidation using an Earth-abundant solid catalyst, cobalt oxide, that allowed us to identify the kinetic bottlenecks. With this knowledge, we can devise and design improvements on the cobalt oxide catalyst and its support environment to partially or completely remove these bottlenecks and improve the efficiency of water oxidation.”
The press release from the DOE/Lawrence Berkeley National Laboratory provides more:
In an artificial photosynthetic system, the oxidation of water molecules into oxygen, electrons and protons (hydrogen ions) provides the electrons needed to produce liquid fuels from carbon dioxide and water. This requires a catalyst that is both efficient in its use of solar photons and fast enough to keep up with solar flux in order to avoid wasting those photons. It should also be robust and affordable on a large-scale. Five years ago, a study led by Frei identified cobalt oxide in the form of single crystal nanoparticles as an excellent candidate for meeting the challenge. However, realizing the full catalytic potential of cobalt oxide nanocrystals requires a better understanding of the individual events in the four-electron cycle of water oxidation.
To provide this understanding, Frei, working with Miao Zhang and Moreno de Respinis, used a spectroscopic technique known as rapid-scan Fourier transform infrared (FTIR) spectroscopy.
“Prior to our study, it was not known whether the catalysis, which takes place on the surface of the cobalt oxide crystallites, happens at every cobalt center on the surface at the same speed, or whether a subset of cobalt sites does most of the work while other subsets are slow or merely spectators,” Frei states. “Our results show that there is a subset of fast sites where a considerable fraction of the catalysis takes place, and a subset of sites where the catalysis proceeds considerably more slowly. This discovery of these fast and slow sites and the proposed structural difference between two provides the basis for designing cobalt oxide surfaces with higher concentrations of fast sites.”
The new findings are detailed in a paper published in the journal Nature Chemistry.
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