Published on August 3rd, 2013 | by James Ayre25
Graphene Supercapacitors — Next-Generation Energy Storage Now One Step Closer
August 3rd, 2013 by James Ayre
Supercapacitors — which are typically composed of highly porous carbon that is impregnated with a liquid electrolyte — are known for possessing an almost indefinite lifespan and the impressive ability to recharge extremely rapidly, in seconds even. But existing versions also possess a very low energy-storage-to-volume ratio — in other words, a low energy density. Because of this low energy density — 5-8 Watt-hours per liter in most supercapacitors — they’re not practical for most purposes. They would either need to be extremely large or be recharged very, very often for most uses.
Monash University continues:
Graphene, which is formed when graphite is broken down into layers one atom thick, is very strong, chemically stable and an excellent conductor of electricity. To make their uniquely compact electrode, Professor Li’s team exploited an adaptive graphene gel film they had developed previously. They used liquid electrolytes — generally the conductor in traditional supercapacitors (SCs) — to control the spacing between graphene sheets on the sub-nanometer scale. In this way the liquid electrolyte played a dual role: maintaining the minute space between the graphene sheets and conducting electricity.
Unlike in conventional, “hard” porous carbon, where space is wasted with unnecessarily large “pores,” density is maximized without compromising porosity in Professor Li’s electrode. To create its material, the research team used a method similar to that used in traditional paper-making, meaning the process could be easily and cost-effectively scaled up for industrial use.
“We have created a macroscopic graphene material that is a step beyond what has been achieved previously. It is almost at the stage of moving from the lab to commercial development,” explained Professor Li.