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Clean Power An atomic-force microscope image of a layer of single-walled carbon nanotubes deposited on a silicon surface, as the first step in manufacturing the new type of solar cell developed by an MIT team. Individual nanotubes can be seen in the image.  Photo: Rishabh Jain et al

Published on June 22nd, 2012 | by Zachary Shahan

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All-Carbon Solar Cell Harnesses Infrared Light

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June 22nd, 2012 by Zachary Shahan
 
 
Here’s some fun and exciting news from researchers at MIT about a new type of photovoltaic device that can harness the heat radiation that most solar cells ignore. Enjoy! (The news was received via email, but it has also been published at the MIT News Office.)

An atomic-force microscope image of a layer of single-walled carbon nanotubes deposited on a silicon surface, as the first step in manufacturing the new type of solar cell developed by an MIT team. Individual nanotubes can be seen in the image. Photo: Rishabh Jain et al

CAMBRIDGE, MA. — About 40 percent of the solar energy reaching Earth’s surface lies in the near-infrared region of the spectrum — energy that conventional silicon-based solar cells are unable to harness. But a new kind of all-carbon solar cell developed by MIT researchers could tap into that unused energy, opening up the possibility of combination solar cells — incorporating both traditional silicon-based cells and the new all-carbon cells — that could make use of almost the entire range of sunlight’s energy.

“It’s a fundamentally new kind of photovoltaic cell,” says Michael Strano, the Charles and Hilda Roddey Professor of Chemical Engineering at MIT and senior author of a paper describing the new device that was published this week in the journal Advanced Materials.

The new cell is made of two exotic forms of carbon: carbon nanotubes and C60, otherwise known as buckyballs. “This is the first all-carbon photovoltaic cell,” Strano says — a feat made possible by new developments in the large-scale production of purified carbon nanotubes. “It has only been within the last few years or so that it has been possible to hand someone a vial of just one type of carbon nanotube,” he says. In order for the new solar cells to work, the nanotubes have to be very pure, and of a uniform type: single-walled, and all of just one of nanotubes’ two possible symmetrical configurations.

Other groups have made photovoltaic (PV) cells using carbon nanotubes, but only by using a layer of polymer to hold the nanotubes in position and collect the electrons knocked loose when they absorb sunlight. But that combination adds extra steps to the production process, and requires extra coatings to prevent degradation with exposure to air. The new all-carbon PV cell appears to be stable in air, Strano says.

The carbon-based cell is most effective at capturing sunlight in the near-infrared region. Because the material is transparent to visible light, such cells could be overlaid on conventional solar cells, creating a tandem device that could harness most of the energy of sunlight. The carbon cells will need refining, Strano and his colleagues say: So far, the early proof-of-concept devices have an energy-conversion efficiency of only about 0.1 percent.

But while the system requires further research and fine-tuning, “we are very much on the path to making very high efficiency near-infrared solar cells,” says Rishabh Jain, a graduate student who was lead author of the paper.

Because the new system uses layers of nanoscale materials, producing the cells would require relatively small amounts of highly purified carbon, and the resulting cells would be very lightweight, the team says. “One of the really nice things about carbon nanotubes is that their light absorption is very high, so you don’t need a lot of material to absorb a lot of light,” Jain says.

Typically, when a new solar-cell material is studied, there are large inefficiencies, which researchers gradually find ways to reduce. In this case, postdoc and co-author Kevin Tvrdy says, some of these sources of inefficiency have already been identified and addressed: For instance, scientists already know that heterogeneous mixtures of carbon nanotubes are much less efficient than homogeneous formulations, and material that contains a mix of single-walled and multiwalled nanotubes are so much less efficient that sometimes they don’t work at all, he says.

“It’s pretty clear to us the kinds of things that need to happen to increase the efficiency,” Jain says. One area the MIT researchers are now exploring is more precise control over the exact shape and thickness of the layers of material they produce, he says.

The team hopes that other researchers will join the search for ways to improve their system, Jain says. “It’s very much a model system,” he says, “and other groups will help to increase the efficiency.”

But Strano points out that since the near-infrared part of the solar spectrum is currently entirely unused by typical solar cells, even a low-efficiency cell that works in that region could be worthwhile as long as its cost is low. “If you could harness even a portion of the near-infrared spectrum, it adds value,” he says.

Strano adds that one of the paper’s anonymous peer reviewers commented that the achievement of an infrared-absorbing carbon-based photovoltaic cell without polymer layers is the realization of “a dream for the field.”

The work also involved MIT graduate students Rachel Howden, Steven Shimizu and Andrew Hilmer; postdoc Thomas McNicholas; and professor of chemical engineering Karen Gleason. It was supported by the Italian company Eni through the MIT Energy Initiative, as well as the National Science Foundation and the Department of Defense through graduate fellowships to Jain and Howden, respectively.

Written by David Chandler, MIT News Office

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About the Author

is the director of CleanTechnica, the most popular cleantech-focused website in the world, and Planetsave, a world-leading green and science news site. He has been covering green news of various sorts since 2008, and he has been especially focused on solar energy, electric vehicles, and wind energy since 2009. Aside from his work on CleanTechnica and Planetsave, he's the founder and director of Solar Love, EV Obsession, and Bikocity. To connect with Zach on some of your favorite social networks, go to ZacharyShahan.com and click on the relevant buttons.



  • icpcwsith

    Anyone found the title of the paper they published  please?

  • http://www.energyquicksand.com/ Edward Kerr

    I can imagine a solar cell that is able utilize the entire electromagnetic spectrum. Able to turn all radiation, from long wave radio all the way up to gamma rays, into an electrical current. (but I can imagine a lot of strange stuff)…

    In any event, it’s good to know that research into advanced “green energy” production capability is continuing in spite of the chaos that has become rampant in the political realm with all of the denial of the problem, finger pointing about “Solyndra” type fiascoes and the childish polarity that defines the parties these days. 

    Regardless, I remain buoyed about the long term outlook providing that we actually develop the “alternatives” presently available as quickly as possible. The main issue here remains being able to abandon First coal and then petroleum as we continue to search for greater efficiency in our developing “New Energy Paradigm”. Logic dictates that we accomplish this task or risk some truly catastrophic consequences.

  • Nameruin

    Seriously?
    “efficiency of only about 0.1 percent” seems like a pretty far and long way from “we are very much on the path to making very high efficiency near-infrared solar cells”…

    • Matt

      Agree 0.1 sounds really low. But efficiency is a interesting number. When you read 12% efficiency for a solar panel it isn’t for the total spectrum or energy that the sun puts out (hits the surface of the earth). It is for the range that it can convert. If that is true then you have to look at a few things. Let me use solar NRG as the solar radition that reaches the ground (your panel). Yes this varis based on local, month, clouds, …

      What portion of the solar NRG is in the band converted by panels (pn%) and panel eff (pe%)

      What portion of the NRG is in the near infrared (rn%) and coating eff (re%)

      Also remember that the solar panel emits most of the NRG it doesn’t convert back out as infrared, but lets ignore that but it would increase the amount to infrared radition that the coating could convert.

      So energey produced by panel is pn*pe*NRG
      energy produced by coating is rn*re*NRG.

      So depending on the rn verse pn they may in fact be close.

    • http://cleantechnica.com/ Zachary Shahan

      this is from MIT. i assume they ran their statements by the researchers… but you never know.

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