Reusable Carbon Nanotube & Quartz Fiber Water Filter Removes 99% Of Heavy Metals

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Researchers at Rice University have developed a simple water filtration material so effective that a single gram of it can treat up to 83,000 liters of contaminated water, after which it can be washed with vinegar and reused.

After a trip to India, where he saw the connection between e-waste and groundwater contamination as a high-schooler, and then working with Rice chemist Andrew Barron, Perry Alagappan, now an undergraduate student at Stanford University, developed a potentially lifesaving filter that has been shown to remove up to 99% of the toxic heavy metals in treated water samples, including lead, copper, cadmium, mercury, and nickel.

Plain quartz fiber, top, gains the ability to remove toxic metals from water when carbon nanotubes are added, bottom. The filters absorbed more than 99 percent of metals from test samples laden with cadmium, cobalt, copper, mercury, nickel and lead. Once saturated, the filters can be washed and reused. (Credit: Barron Research Group/Rice University)
An electron microscope image shows quartz fibers with carbon nanotubes grown in place. Courtesy of the Barron Research Group

The filter material is made from carbon nanotubes which are grown in place on a substrate of quartz fibers (“quartz wool”) and are “then chemically epoxidized.” According to lab tests, the resulting SENT (supported-epoxidized carbon nanotube) filters, when scaled up, are able to quickly (<1 min.) treat 5 liters of contaminated water, and to then be “renewed” in about 90 seconds. To renew the fiber, a “mild household chemical like vinegar” is used to extract the metals for reclamation or proper disposal, after which it regains its adsorption efficiency and can be reused.

In addition to being effective and reusable, the new filter uses inexpensive raw materials (“a cost under $0.25/g including materials and manufacturing costs”) and relies on a fairly easy and common skill — the making of vinegar — to keep it functional and reusable.

“Every culture on the planet knows how to make vinegar.” 

“This would make the biggest social impact on village-scale units that could treat water in remote, developing regions. However, there is also the potential to scale up metal extraction, in particular from mine wastewater.” – Andrew R. Barron, Department of Chemistry, Rice University

For his ongoing research and developments, Alagappan has taken home the top spot in the Environmental Science category of the 2014 Intel International Science and Engineering Fair, and was recognized with the award of the 2015 Stockholm Junior Water Prize.

The full research paper from Alagappan, which was co-authored by Jessica Heimann, Lauren Morrow, Enrico Andreoli, and Andrew R. Barron, is available at the journal Scientific Reports, under the title “Easily Regenerated Readily Deployable Absorbent for Heavy Metal Removal from Contaminated Water.


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Derek Markham

Derek lives in southwestern New Mexico and digs bicycles, simple living, fungi, organic gardening, sustainable lifestyle design, bouldering, and permaculture. He loves fresh roasted chiles, peanut butter on everything, and buckets of coffee.

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