Penn State Researchers Discover Method of Off-Grid Hydrogen Production
September 20th, 2011 by Glenn Meyers
A Penn State research team reports an unlimited supply of pure hydrogen gas can be produced using seawater, river water and organic waste. The news may mean our renewable energy infrastructure will soon undergo a dramatic shift.
According to the Penn State team of Bruce E. Logan, professor of environmental engineering, and postdoctoral fellow Younggy Kim, a grain of salt or two may be all microbial electrolysis cells need to produce hydrogen from wastewater or organic byproducts. They contend this could occur without adding carbon dioxide to the atmosphere or using grid electricity.
“This system could produce hydrogen anyplace that there is wastewater near sea water,” said Logan. “It uses no grid electricity and is completely carbon neutral. It is an inexhaustible source of energy.”
Get prepared for a radical shift in how renewable energy is produced and distributed. Microbial electrolysis cells that produce hydrogen are the basis of this recent work, but previously, to produce hydrogen, the fuel cells required some electrical input. Now, Logan, working with postdoctoral fellow Younggy Kim, is using the difference between river water and seawater to add the extra energy needed to produce hydrogen.
Their results of this research, published in the Sept. 19 issue of the Proceedings of the National Academy of Sciences, “show that pure hydrogen gas can efficiently be produced from virtually limitless supplies of seawater and river water and biodegradable organic matter.”
Logan’s cells were between 58 and 64 percent efficient in producing between 0.8 to 1.6 cubic meters of hydrogen for every cubic meter of liquid through the cell each day. According to a press announcement from Penn State, the researchers estimated that only about 1 percent of the energy produced in the cell was needed to pump water through the system. The research team says the key to these microbial electrolysis cells is reverse-electrodialysis (RED) that extracts energy from the ionic differences between salt water and fresh water. An RED stack consists of alternating ion exchange membranes — positive and negative — with each RED contributing additively to the electrical output.
RED technology to hydrolyze water — split it into hydrogen and oxygen — requires 1.8 volts, which would in practice require about 25 pairs of membrane sand increase pumping resistance. However, combining RED technology with exoelectrogenic bacteria — bacteria that consume organic material and produce an electric current — reduced the number of RED stacks to five membrane pairs.
Previous work with microbial electrolysis cells showed that they could, by themselves, produce about 0.3 volts of electricity, but not the 0.414 volts needed to generate hydrogen in these fuel cells. Adding less than 0.2 volts of outside electricity released the hydrogen. Now, by incorporating 11 membranes — five membrane pairs that produce about 0.5 volts — the cells produce hydrogen. “The added voltage that we need is a lot less than the 1.8 volts necessary to hydrolyze water,” said Logan. “Biodegradable liquids and cellulose waste are abundant and with no energy in and hydrogen out we can get rid of wastewater and by-products. This could be an inexhaustible source of energy.”
Logan and Kim’s research used platinum as a catalyst on the cathode, however, subsequent experimentation has shown that a non-precious metal catalyst, molybdenum sulfide, provided 51 percent energy efficiency.
Pure hydrogen doesn’t occur naturally. Traditional production methods have required significant energy, usually generated by fossil fuels.
This could be the discovery of the century for the renewable energy industry.
Photo: Bruce Logan
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